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Rate constants for the reactions of O+ with N2 and O2 as a function of temperature (300–1800 K)
Hierl, Peter M. Dotan, I. Seeley, John V. Doren, Jane M. Van Morris, Robert A. Viggiano, A. A.
Hierl, Peter M.
Dotan, I.
Seeley, John V.
Doren, Jane M. Van
Morris, Robert A.
Viggiano, A. A.
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Abstract
We have studied the rate constants for the reaction of O+ with N2 over the temperature range 300–1600 K and the reaction of O+ with O2 over the range 300 to 1800 K. The results are in good agreement with previous measurements made up to 900 K. The rate constant for the O+reaction with N2 shows a minimum in the temperature range 1100–1300 K. The increase above this temperature is due to N2 v=2 becoming populated. The rate constant for O++O2 shows a minimum in the 800–1100 K range. Comparing to previous drift tube measurements allows the rate constant for O2 (v>0) to be derived. The v>0 rate constant is approximately five times larger than the v=0 rate constant.
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This is the publisher's version, also available electronically from http://scitation.aip.org/content/aip/journal/jcp/106/9/10.1063/1.473450.
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1997-01-01
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American Institute of Physics
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Hierl, Peter M. et al. (1997). "Rate constants for the reactions of O+ with N2 and O2 as a function of temperature (300–1800 K)." Journal of Chemical Physics, 106:3540-3544. http://dx.doi.org/10.1063/1.473450.