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One-pot synthesis of GABA amides via the nucleophilic addition of amines to 3, 3-disubtituted cyclopropenes
Maslivetc, Vladimir A. Rubina, Marina Rubin, Michael
Maslivetc, Vladimir A.
Rubina, Marina
Rubin, Michael
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Abstract
A one-pot synthesis of various GABA amides has been demostrated, employing the nucleophilic addition of primary and secondary amines across the double bond of cyclopropene-3-carboxamides, followed by ring-opening of the resulting donor-acceptor cyclopropanes and subsequent in situ reduction of enamine (imine) intermediates.
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2015-09-14
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Royal Society of Chemistry
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Maslivetc_2015.pdf
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Maslivetc, V. A., Rubina, M., & Rubin, M. (2015). One-pot synthesis of GABA amides via the nucleophilic addition of amines to 3,3-disubstituted cyclopropenes. Organic & Biomolecular Chemistry, 13(34), 8993–8995. http://doi.org/10.1039/c5ob01462j