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Facile assembly of 1,5-diazocan-2-ones via cyclization of tethered sulfonamides to cyclopropenes
Matheny, Jonathon P. Yamanushkin, Pavel M. Petillo, Peter A. Rubin, Michael
Matheny, Jonathon P.
Yamanushkin, Pavel M.
Petillo, Peter A.
Rubin, Michael
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Abstract
The sulfonamide moiety was evaluated as an activating and stabilizing functional group in the metal-templated strain release-driven intramolecular nucleophilic addition of amines to cyclopropenes to generate 1,5-diazocan-2-ones.
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2020-12-15
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Royal Society of Chemistry
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Matheny JP, Yamanushkin PM, Petillo PA, Rubin M. Facile assembly of 1,5-diazocan-2-ones via cyclization of tethered sulfonamides to cyclopropenes. RSC Adv. 2020 Dec 15;10(72):44183-44190. doi: 10.1039/d0ra09014j. PMID: 35517142; PMCID: PMC9058510.