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Phosphate Tether-Mediated Ring-Closing Metathesis for the Generation of Medium to Large, P-Stereogenic Bicyclo[n.3.1]phosphates
Maitra, Soma Markley, Jana L. Chegondi, Rambabu Hanson, Paul R.
Maitra, Soma
Markley, Jana L.
Chegondi, Rambabu
Hanson, Paul R.
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Abstract
A phosphate tether-mediated ring-closing metathesis study towards the synthesis of P-stereogenic bicyclo[6.3.1]-, bicyclo[7.3.1]-, and bicyclo[8.3.1]phosphates is reported. This study demonstrates expanded utility of phosphate tether-mediated desymmetrization of C2-symmetric, 1,3-anti-diol dienes in generating complex medium to large, P-stereogenic bicyclo[n.3.1]phosphates..
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Date
2015-09-02
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Elsevier
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Keywords
Phosphate tether, Tripodal coupling, P-stereogenic phosphate, Ring-closing metathesis, Bicyclic phosphate triester, Desymmertrization
Citation
Maitra, Soma et al. “Phosphate Tether-Mediated Ring-Closing Metathesis for the Generation of Medium to Large, P-Stereogenic Bicyclo[n.3.1]phosphates.” Tetrahedron 71.35 (2015): 5734–5740.