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Deacylative allylation of nitroalkanes: unsymmetric bisallylation via 3-component coupling
Grenning, Alexander J. Tunge, Jon A.
Grenning, Alexander J.
Tunge, Jon A.
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Abstract
Use it and lose it! Allylic alcohols were used directly for the synthesis of diallylated nitroalkanes in a three-component coupling based on the strategy of deacylative allylation for the in situ generation of a nucleophile and an allyl electrophile (see scheme).
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2011-02-11
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Wiley
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Grenning_ACIEE_2011.pdf
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Deacylation, Tsuji-Trost reaction, Nitroalkane allylation, 1, 6-diene synthesis
Citation
Grenning, A. J., & Tunge, J. A. (2011). Deacylative allylation of nitroalkanes: unsymmetric bisallylation via 3-component coupling. Angewandte Chemie (International Ed. in English), 50(7), 1688–1691. http://doi.org/10.1002/anie.201006273