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Encapsulation and selective recognition of sulfate anion in an azamacrocycle in water
Mendy, John S. ; Pilate, Marcy L. ; Horne, Toyketa ; Day, Victor W. ; Hossain, Alamgir
Mendy, John S.
Pilate, Marcy L.
Horne, Toyketa
Day, Victor W.
Hossain, Alamgir
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Abstract
Structural characterization of a sulfate complex with an azamacrocycle suggests that one sulfate is encapsulated in the macrocyclic cavity with eight hydrogen bonds; a significant selectivity of the host was observed for sulfate over halides, nitrate and perchlorate as evaluated by 1H NMR studies in water.
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2010-09-07
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Royal Society of Chemistry
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Mendy, J. S., Pilate, M. L., Horne, T., Day, V. W., & Hossain, M. A. (2010). Encapsulation and selective recognition of sulfate anion in an azamacrocycle in water. Chemical Communications (Cambridge, England), 46(33), 6084–6086. http://doi.org/10.1039/c0cc01699c