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Electrophilic activation of nitroalkanes in efficient synthesis of 1,3,4-oxadiazoles
Aksenov, Alexander V. Khamraev, Vladislav Aksenov, Nicolai A. Kirilov, Nikita K. Domenyuk, Dmitriy A. Zelensky, Vladimir A. Rubin, Michael
Aksenov, Alexander V.
Khamraev, Vladislav
Aksenov, Nicolai A.
Kirilov, Nikita K.
Domenyuk, Dmitriy A.
Zelensky, Vladimir A.
Rubin, Michael
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Abstract
A novel methodology for general and chemoselective preparation of non-symmetric 1,3,4-oxadiazoles is developed. This unusual reaction proceeds via polyphosphoric acid-assisted activation of nitroalkanes towards nucleophilic attack with acylhydrazides.
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This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
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2019-02-26
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Royal Society of Chemistry
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Alexander V. Aksenov, V. Khamraev, N. A. Aksenov, N. K. Kirilov, D. A. Domenyuk, V. A. Zelensky and M. Rubin, "Electrophilic activation of nitroalkanes in efficient synthesis of 1,3,4-oxadiazoles", RSC Adv., 2019, 9, 6636, DOI: 10.1039/C9RA00976K