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Phosphate Tether-Mediated Ring-Closing Metathesis Studies to Complex 1,3-anti-Diol-Containing Subunits

Chegondi, Rambabu
Maitra, Soma
Markley, Jana L.
Hanson, Paul R.
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Abstract
An array of examples of diastereoselective, phosphate tether-mediated ring-closing metathesis reactions, which highlight the importance of product ring size and substrate stereochemical compatibility, as well as complexity, is reported. Studies focus primarily on the formation of bicyclo[n.3.1]phosphates, involving the coupling of C2-symmetric dienediol subunits with a variety of simple, as well as complex alcohol cross-partners.
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This is the peer reviewed version of the following article: Chegondi, R., Maitra, S., Markley, J. L., & Hanson, P. R. (2013). Phosphate Tether-Mediated Ring-Closing Metathesis Studies to Complex 1,3-anti-Diol-Containing Subunits. Chemistry (Weinheim an Der Bergstrasse, Germany), 19(25), 10.1002/chem.201300913. http://doi.org/10.1002/chem.201300913, which has been published in final form at doi.org/10.1002/chem.201300913. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
Date
2013-06-17
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Wiley
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Keywords
Phosphate tether, Diastereotopic differentiation, Ring-closing metathesis, Bicyclic phosphate, Natural products
Citation
Chegondi, R., Maitra, S., Markley, J. L., & Hanson, P. R. (2013). Phosphate Tether-Mediated Ring-Closing Metathesis Studies to Complex 1,3-anti-Diol-Containing Subunits. Chemistry (Weinheim an Der Bergstrasse, Germany), 19(25), 10.1002/chem.201300913. http://doi.org/10.1002/chem.201300913
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