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Formal [4+3] Epoxide Cascade Reaction via a Complementary Ambiphilic Pairing Strategy

Rolfe, Alan
; 
Samarakoon, Thiwanka Bandara
; 
Hanson, Paul R.
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Abstract
A formal [4+3] epoxide cascade protocol utilizing ambiphilic sulfonamides and a variety of epoxides (masked ambiphiles) has been developed for the generation of benzothiaoxazepine-1,1′-dioxides and oxathiazepine-1,1′-dioxides. This protocol combines an epoxide ring-opening with either an SNAr or oxa-Michael cyclization pathway.
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Date
2010-03-19
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American Chemical Society
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Chemistry Scholarly Works
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Rolfe, A., Samarakoon, T. B., & Hanson, P. R. (2010). Formal [4+3] Epoxide Cascade Reaction via a Complementary Ambiphilic Pairing Strategy. Organic Letters, 12(6), 1216–1219. http://doi.org/10.1021/ol100035e
URI
https://hdl.handle.net/1808/23472
DOI
10.1021/ol100035e
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